Disheveled
Appearance
The word often describes a messy look, so it's used in contexts of disarray.

He looked disheveled after the long flight.
Negative connotation
While it can imply a relaxed style, it often has a negative edge suggesting neglect.

She appeared disheveled and unprepared for the meeting.
Emotional state
Disheveled can also metaphorically reflect an emotional state of chaos or overwhelm.

He felt disheveled after the stressful week.
Compare with
tidyscruffychaoticmessyunkempt
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